ZSM-5分子筛酸分布对丁烯裂解制丙烯性能的影响.pdfVIP

学兔兔 石 油 化 工 · 926· PETROCHEMICAL TECHN0L0GY 201 1年第40卷第9 ～发一 一开一 一与一 一究一 ～研一 ZSM一5分子筛酸分布对丁烯裂解制 丙烯性能的影响 张新元，张 飞，张明森 (中国石化 北京化工研究院，北京 100013) [摘要]以硝酸钙为改性剂处理ZSM一5分子筛孔道内及外表面的酸中心，得到一系列酸分布不同的钙改性ZSM一5分子筛胜化 剂，并采用XRD，SEM，BET，XRF，NH3一TPD等技术对催化剂的物化性质进行表征；在连续流动固定床反应器卜直圩究r分子筛孔 道内及外表面的酸分布对丁烯裂解制丙烯反应性能的影响。实验结果表明，钙改性ZSM一5分子筛的酸量是丁烯裂解活性的决 定因素，酸量越多，催化剂催化丁烯裂解的活性越高；丙烯选择性主要受催化剂酸强度的影响，降低酸强度有利于提高阿烯选择 性；ZSM一5分子筛外表面酸中心在丁烯催化裂解制丙烯过程中起主要作用，改性时保留外表面酸中心肯利于提高丙烯选择性 [关键词]ZSM一5分子筛；表面酸性；丁烯；丙烯；催化裂解 [文章编号]1000—8144(2011)09—0926—06 [中图分类号]TQ 426．95 [文献标识码]A Effect of ZSM-5 Zeolite Acid Distribution on Butene Cracking to Propylene Zhang Xinyuan，Zhang Fei，Zhang Mingsen (Beijing Research Institute of Chemical Industry，SINOPEC，Beijing 100013，China) [Abstract]A series of ZSM一5 catalysts with different acid distribution were prepared by the treatment 0f the acid centers located on the zeolite channel and／or outer surface with calcium nitrate as the modifier．The catalysts were characterized by means of XRD，SEM，BET，XRF and NH3-TPD．The effect of the ZSM一5 acid distribution on butene cracking to propylene was investigated on a continuous fixed—bed reactor．The results manifested that the butane conversion was determined by the acid amount and raised with increasing of the acid amount．Propylene selectivity was influenced mainly by the acid strength and low acid strength was bene