低氧浓度下煤燃烧特性的热重实验研讨.pdfVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：094182 低氧浓度下煤燃烧特性的热重实验研究 王长安，刘银河，车得福 （西安交通大学动力工程多相流国家重点实验室，西安，710049） （Tel Email：lvcha1208@stu.xjtu.edu.cn ） 摘要：煤燃烧的部分过程是在低氧浓度下进行的，本文利用热重实验研究煤在低氧浓度下燃烧特性的 变化，重点研究着火特性、燃尽特性和燃烧速率的变化；同时计算分析低氧浓度下，煤燃烧反应动力 学参数的变化。实验结果表明，低氧浓度下煤燃烧反应的TG 和DTG 曲线均向高温区靠近，着火温度 基本不变，燃尽温度提高，燃烧速率下降；低氧浓度下燃烧反应的动力学参数活化能E 和频率因子k0 之间存在着补偿效应。 关键字：低氧浓度，燃烧特性，热重分析，动力学参数 Experimental Investigation on Combustion Characteristics of Coals in Low Oxygen Concentration with Thermogravimetry WANG Chang-An, LIU Yin-He, CHE De-Fu (State Key Laboratory of Multiphase Flow for Power Engineering, Xi’an Jiaotong University, Xi’an 710049) Abstract: Parts of coal combustion carry on in low oxygen concentration. The combustion characteristics of coals in low oxygen concentration was investigated by the use of thermogravimetry, and ignition characteristics, burn-out characteristics and change of combustion rate were mainly studied. We also calculated the changes of kinetic parameters of coal combustion in low oxygen concentration. Thermogravimetric experiment shows that, coal combustion TG and DTG curves of all pulverized coals move to higher temperature zone in lower oxygen concentration, the ignition temperature is almost constant, the temperature of burn-out increases and the combustion rate decreases. Compensation effect exists between kinetic parameters of combustion reaction the activation energy E and frequency factor k0. Keywords: low oxygen concentration, combustion characteristics, thermogravimetric analysis, kinetic parameters 0 引言 我国常规能源以煤炭为主，据预测，到2050 年煤炭在我国能源中的比例仍占50% [1] 以上 ，然而煤炭利用过程中存在着利用效率低、污染严重等问题。深入研究煤的燃烧 特性，对于推进煤炭清洁燃烧，提高我