β-羟乙基砜硫酸酯活性染料中间体的合成及绿色工艺优化word论文.docxVIP

在某些重要的性能上，例如上染率、固色率、得色量等方面有不少的提升，有望取代旧的对位酯，应用前景良好。关键词：活性染料，中间体，固色率，工艺2Theoptimalgreentechnologyforthesynthesisofβ-hydroxyethylsulfonesulfateintermediatesforreactivedyesAbstractInrecentyears,studyonofreactivedyeshasgraduallybecomeahotspotin dyestuffindustry.Somematuretechnologiesproducingreactivedyesstillhavemany shortcomings.Forexample:thesynthesisoftheintermediatesanddyeswillgeneratea lotofcoloredwatsewater,andthelowutiliforzationofthedyes,thelowreactivedye fixationandtheinsufficientcolorfastnessetc.Thesewilleventuallyleadtoaseriesof ecologicalproblemsofenvironmentalpollutionandatomeconomy.However,thehigh fixationrateisthetopissueofreactivedyeswhichcansavedyesandreducepollution. It has becomeamajorresearch trend.Theaimofthispaperistosynthesizeanewreactiveintermediates,whichhas improvedwatersolubilityandiseasytobecombinedwiththedyeparentsforwideand practicalapplication.Allthesewillimprovetheutilizationandfixationrateofthedyes. Thestructuresofthesynthesizedcompoundsarecharacterizedby1HNMR,13CNMR, andFT-IRspectra.What’smore,theoptimalconditionsandagreeneconomyroutefor thesynthesiswillbeexploredtogethighyieldinordertomeettherequirementsofthe contemporaryproductionprocess.Themain research contents are as follows:Synthesisofcompound5,β-hydroxyethylsulfonesulfateintermediatesfor reactivedyes.Bythereactionbetweenβ-mercaptoethanoland2-chloroethylamine hydrochlorideunderthealkalinecondition,thethioether-basedcompound1canbe obtained.The amiditionreactionof1withp-nitrobenzoylchlorideundertheice-cooling3conditionaffordedcompound2inabout90%yield.Compound3,wasobtainedby oxidationreactionof2undertheacidicconditionwithhydrogenperoxideinupto95% yield.Aminecompound4wasobtainedbyeithertheuseofhydrazinehydrateand Raneynickel or Raneynickel and hydrogen, the formergivingayield above80%, while thelattercloseto100%.Thefinalintermediatescompound5canbeobtainedwhenthe compound4isheatedwiththeconcentratedsulfuricacid,whichhasaivorywhite appearanceanditsaminovalueis94.6%,thevalueofesterificati