lasr3fe3xmnxo10δ和lasr3fe3o10ce0.8sm0.2o2混合导体制备及性能研究-lasr3fe3xmnxo10d和lasr3fe3o10ce 0.8 sm 0.2 o2hunhedaotizhibeijixingnengyanjiu.docxVIP

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lasr3fe3xmnxo10δ和lasr3fe3o10ce0.8sm0.2o2混合导体制备及性能研究-lasr3fe3xmnxo10d和lasr3fe3o10ce 0.8 sm 0.2 o2hunhedaotizhibeijixingnengyanjiu.docx

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lasr3fe3xmnxo10δ和lasr3fe3o10ce0.8sm0.2o2混合导体制备及性能研究-lasr3fe3xmnxo10d和lasr3fe3o10ce 0.8 sm 0.2 o2hunhedaotizhibeijixingnengyanjiu

ABSTRACTThe perovskite structure of oxides have a wide range of technical application in catalysis, SOFC and oxygen sensor et al.The structures, electrical property, oxygen diffusion mechanism and the cathode electrochemical performance of LaSr3Fe3-xMnxO10-δ mixed conductor and LaSr3Fe3O10-Ce0.8Sm0.2O2 dual phase materials were studied in this paper.LaSr3Fe3-xMnxO10-δ (x=0.0-0.8) mixed conductors with layered perovskite structure were prepared via citric acid method. XRD analysis showed that the cell volume decreased with Mn content. The fraction of Fe4+ concentration to the concentration of tetravalent ions decreased with the increase of Mn content. The decrease of VB of LaSr3Fe3-xMnxO10-δ samples with the increase of temperature gave rise to the drop of p type charge carriers and the increase of oxygen vacancies. The formula of the relationship between VB and the numbers of the configurations of transition metals in LaSr3Fe3-xMnxO10-δ was deduced and hence the possible filling states of 3d orbitals ofFe and Mn ions at 700℃ and 800℃ were given. Scanning Kelvin probe measurementresults revealed that the surface potential of x=0.6 sample was the highest while x=0.8 sample was the lowest. The higher the surface potential, the higher the energy needed for an electron to be released from the sample. The coefficient of oxygen diffuse was measured by method of electrical conductivity relaxation. The oxygen diffusion coefficients increase with the temperature while decrease with the manganese content (x≤ 0.4 range) .The apparent activation energy Ea decreased with the Mn-doped quantity .The dual phase specimen of LaSr3Fe3O10-Ce0.8Sm0.2O2 were perpared by means of solid state reaction.By using four-terminal method, the LaSr3Fe3O10-Ce0.8Sm0.2O2 dual phase specimen conductivity were studied. The maximum conductivity of LSFO-SDC dual phase specimen offset to the high temperature with the increased SDC-doped quantity .Among that, the conductivity properties of LSFO-SDC=2:8 was