不同主链和侧基液晶基元连接方式的改变对聚合物液晶行为的影响分析-高分子化学与物理专业论文.docxVIP

湘潭大学硕士学位论文 湘潭大学硕士学位论文 II II Abstract Polyacrylate side-chain liquid-crystalline polymer, one of the SCLCPs, has attracted considerable interest in so many fields with great potential application in information storage and gas chromatographic analysis. The molecular structure of SCLCPs is consists of four parts: the polymer chain, the flexible spacer, mesogenic unit and the end groups. Depending on the position where the mesogens are linked to the backbone, the mesogen can be either longitudinally or laterally attached into the polymeric system. Thus SCLCPs with a longitudinal connection (end-on) of the mesogen are end-on SCLCPs and those with lateral connection (side-on) are called side-on SCLCPs. It is well-known that mesogen-jacketed liquid crystal polymers (MJLCPs) have the typical chemical structure as side-chain liquid crystal polymers and properties as main -chain liquid crystal polymers.This paper mainly focuses on studying the effection of polymer backbone and connection type of mesogens on the liquid crystalline behavior of polyacrylates. The works are mainly divided into the following two aspects. Firstly, four kinds of monomers are designed and synthesized with the name of 2,5-bis [(p-methoxyphenoxy) carbonyl] benzyl methacrylate) , 2,5-bis (4’-methoxybenzoyloxy) benzyl methacrylate， 2,5-bis [(p-methoxyphenoxy) carbonyl] benzyl acrylate and 2,5-bis (4’-methoxybenzoyloxy) benzyl acrylate. The molecular structure of these monomers is performed with 1H NMR and 13C NMR. The phase structures and transition behaviors of the monomers are studied by using differential scanning calorimetry (DSC) and polarized optical microscope (POM). Through those efforts, we find that the monomers are thermosensitive liquid crystal except monomer M1 and M2, and the liquid-crystalline behavior of the monomers is depended on the chemical structure obviously. And it is difficult to identify the LC pahse because of the lability of monomer M2. Secondl