松嫩平原含水层沉积物特征及其对砷赋存态分布影响.docVIP

松嫩平原含水层沉积物特征及其对砷赋存态分布影响 　　摘 要： 松嫩平原西部地区为中国砷中毒区域，含水层沉积物特征及砷赋存态对地下水砷迁移、转化的影响并不清楚。在对研究区高砷区与低砷区钻孔沉积物进行取样的基础上，运用激光粒度分析、Tessier五步提取法和Keon分步提取法分别确定了不同深度沉积物的粒度分布和不同赋存态砷含量，系统研究了沉积物的水力传导系数、不同赋存态砷的分布及其与高砷地下水形成的关系。结果表明：沉积物5种赋存态砷（包括可交换态、碳酸盐吸附态、铁/锰氧化物吸附态、有机物或硫化物吸附态和基质态）中，铁/锰氧化物吸附态砷含量最高，并且砷含量与铁、锰含量呈明显正相关性； 高砷区钻孔沉积物铁/锰氧化物吸附态砷质量分数为（1.18～6.11）×10-6，低砷区为（0.67～2.60）× 10-6；高砷区钻孔沉积物以粉砂、黏土为主，水力传导系数介于0.004～0.027 m?d-1，低砷区钻孔沉积物以细砂、中砂为主，水力传导系数介于0.005～0.2 m?d-1；沉积物中粉砂或黏土含量越多，则沉积物颗粒越小，其水力传导系数越低，各赋存态砷含量越高，因此，高砷区低水力传导系数有利于还原环境的形成。通过地下水的循环，高砷含水层沉积物的淋滤作用和铁/锰氧化物的还原性溶解形成了研究区高砷地下水。 　　关键词： 地下水；砷；沉积物；赋存态；粒度；连续提取；水力传导系数；松嫩平原 　　中图分类号： P641.3 文献标志码： A 　　Abstract： The western Songnen Basin is one of typical arsenic poisoning regions in China. However， the effects of sediment characteristics and arsenic occurrence modes on groundwater arsenic migration are still unknown. Based on sediment sampling from boreholes with high or low contents of arsenic， particle size distributions and contents of different arsenic occurrence modes of sediments in different depths were analyzed by laser particle size analyzer， Tessier five-step extraction method and Keon step-by-step extraction method. The roles of hydraulic conductivity coefficient and distribution of different arsenic occurrence modes of sediments in forming groundwater with high content of arsenic were investigated. The results show that content of Fe/Mn oxide absorbed arsenic， which has significantly positive correlation with contents of Fe and Mn， is the highest among the five arsenic occurrence modes including exchangeable， carbonate absorbed， Fe/Mn oxide absorbed， organic or sulfide absorbed and metrical modes； mass fractions of Fe/Mn oxide absorbed arsenics are （1.18-6.11）×10-6 and （0.67-2.60）×10-6 for the sediments from boreholes in the area with high or low contents of arsenic； the sediments from boreholes in the area with high content of arsenic are mainly silt and clay with the hydraulic conductivity coefficient of 0.004-0.027 m?d-1， and the sed