交联改性丙烯酸酯乳液的合成及其在凹印水性油墨中的应用分析-材料学工程专业论文.docxVIP

摘 要 随着人们绿色环保意识的不断提高，对印刷品要求也越高，水性 油墨因其低挥发性，减轻了大气污染，同时降低了溶剂在包装中的残 留，得到广泛应用。 1、本文以甲基丙烯酸甲酯（MMA）、丙烯酸丁酯（BA）和丙烯 酸（AA）为单体，以过硫酸铵（APS）为引发剂，以烷基酚聚氧乙 烯醚（OP-10）和十二烷基苯磺酸钠（SDS）为乳化剂，以去离子水 为溶剂，采用半乳化法合成水性丙烯酸树脂。通过研究未改性丙烯酸 酯乳液的化学试剂用量和工艺条件不同对性能的影响，确立了合成油 墨用水性丙烯酸树脂的最佳方案为全部预乳化半连续法合成，软硬单 体最佳质量配比为 45.0/53.0，乳化剂用量为单体质量的 3%，且 SDS/OP-10 比例为 5:1，反应温度设置于 75℃~90℃。 2、以甲基丙烯酸甲酯、丙烯酸丁酯、丙烯酸为共聚单体，双丙 酮丙烯酰胺(DAAM)为功能单体。采用半连续法乳液聚合技术，合成 含有酮羰基的聚丙烯酸酯乳液。以己二酸二酰肼为交联剂，获得的丙 烯酸酯乳液在室温贮存时不产生交联反应，而在干燥时由于体系 pH 值发生变化，在酸的催化下固化成膜。研究结果表明,加入 3%DAAM 制得的丙烯酸酯乳液固含量达 50%左右。粒径主要分布在 68.1nm 左 右，并具有分布窄的特点，室温交联胶膜透明度、光泽度高，成膜速 度快，各项性能更加优异。 3、采用半连续乳化法制备了双丙酮丙烯酰胺-己二酸二酰肼改性 的丙烯酸酯乳液，配以蓝色碱性颜料配制成水性油墨。讨论了交联体 系改性对水性油墨各性能的影响。结果表明，随着 DAAM-ADH 含量 由 0%增加到 3%，丙烯酸酯乳液固含量增加，粒径变小，水性油墨的 粘度增大，稳定性得到了改善，附着牢度增大，耐水性耐酸碱性增强， 可以满足粘度、细度、附着力及初干性等凹版印刷适性的要求。 关键词：水性丙烯酸酯乳液，水性油墨，交联改性，双丙酮丙烯酰胺， 凹版印刷 I ABSTRACT With the continuous improvement of people’s environmental consciousness and the higher requirements of print, water -based ink are used widely because of its low volatility to reduce air pollution and reduce the residual solvent in the packaging at the same time. 1、Polyacrylate emulsion was obtained by semi-continuous emulsion polymerization with methyl methacrylate, butyl acrylate, acrylic acid as monomers; ammonium persulfate as initiator; alkylphenol ethoxylates and sodium dodecyl benzene sulfonate as emulsifier and deionized water as solvent. Through the research of the influence of different dosages of drugs and different technological conditions on the performance of water-based acrylate emulsion, established the best solution for the aqueous acrylic resin emulsion semi-continuous synthesis with all pre-emulsifier, monomers optimum ratio of 45.0/53.0, and the amount of emulsifier is 3% of monomer and the quality of SDS/OP-10 proportion of 5:1, the reaction temperature set at 78℃ to 90℃. 2、Polyacrylate emulsion containing ketone carbonyl was obtained by semi-continuous emulsion polymerization with methyl methacrylate, butyl acrylate, acrylic acid as co-mono