减压间歇精馏分离蒎烯系列香料的研究-化学工艺专业论文.docxVIP

摘要摘要 摘要 摘要 橙花醇、香叶醇、乙酸芳樟酯和乙酸香叶酯(指乙酸香叶酯和乙酸橙花酯的 混合物)是13一蒎烯路线合成香料中的重要产品。本文以B一蒎烯路线生产的混 合醇产品(香叶醇和橙花醇的混合物)以及生产过程中的中间产物乙酸酯类混合 物(乙酸芳樟酯、乙酸香叶酯)为原料，创新性地进行了产品深度开发研究，得 到了符合高标准质量及收率要求的香叶醇、橙花醇、乙酸芳樟酯和乙酸香叶酯四 种产品，为工业化生产奠定了坚实的基础。 以13一蒎烯路线生产的香叶醇和橙花醇混合醇产品为原料，采用减压间歇精 馏和闪蒸方法，通过添加络合剂提高产品的质量，实现了沸点差仅为2℃的橙花 醇和香叶醇的分离。确定了适宜的变回流比、络合剂用量等条件，获得了含量 90％以上的单一产品，橙花醇产品的收率为86％，香叶醇产品的收率为60％。 以13一蒎烯路线生产过程的中间产物乙酸芳樟酯混合物、乙酸香叶酯混合物 为原料，采用减压间歇精馏，通过添加络合剂，实现了两种热敏性物料的提纯。 确定了适宜的变回流比、物料在瓷环填料和。环金属丝网填料精馏塔中的热分解 温度，获得了含量在95％以上的乙酸芳樟酯产品、乙酸香叶酯产品，产品的收率 分别为80％和68％。 关键词：热敏物料 减压间歇精馏 橙花醇 香叶醇 乙酸芳樟酯 乙酸橙花酯 乙酸香叶酯 ABSTRACTA。BSTRACT ABSTRACT A。BSTRACT Geraniol，nerol，linalyl acetate and neryl acetate(mixture of genaryl acetate and neryl acetate)ale the main synthetic perfume produced from 13-pinene．In this article， creative and advanced methods were developed to separate geraniol and nerol from the mixture of them．Recovery methods were also developed to obtain linatyl acetate and neryl acetate from different semifinished products respectively．Geraniol，nerol， linalyl acetate and neryl acetate of hi曲quality were gained in high yield．The experiment results provide the fundamental data for perfume industry． The mixture produced from 13一pinene mainly containing geraniol and nerol， whose difference in boiling—point is only 2 oC．They were separated by using the method of vacuum batch distillation and flash distillation with additives．Suitable reflux ratio and quantities of additives were discussed and determined．Geraniol product was gained with purity above 90％and yield up to 86％，and nerol product was gained埘_cll purlty above 90％and yield up t0 60％． Semifinished products from 13-pinene contain linalyl acetate，neryl acetate，which are both heat—sensitive materials．Their purification from different semifmished products was carried out respectively,using the method of vacuum batch distillation wim additives．Suitable reflux ratio and the heat—sensitive temperature were discussed and determined．Linalyl acetate product was gained with purity above 9