吸附相反应技术制备以石墨烯为载体的多组分光催化剂.docVIP

PAGE PAGE 20 吸附相反应技术制备以石墨烯为载体的多组分光催化剂 摘要：本次实验的目的是利用水热法把GO和钛酸四丁酯结合并制备出来，最后形成TiO2/GO复合光催化剂。本实验比较创新的研究点是研究该催化剂是否能在海水体系下降解苯酚溶液。实验之前我们利用了TEM透射电子显微镜，傅立叶红外光谱，紫外漫反射分析光谱等首先对载体GO和复合光催化剂进行了一系列的表征，研究和观察其性质。实验之前我们先做了不同浓度下海水体系下苯酚标准曲线，发现海水浓度对其没有影响。经过实验研究发现，复合催化剂制备过程随着加去离子水量越来越多，影响了TiO2粒子在GO表面的附着数量以及粒径大小。经过了一系列的预实验与实验，结合图，我们发现复合催化剂对其有着一定的降解作用，但是半小时以后可能由于催化剂失活导致降解速率下降。由于实验数据量还远远不够，实验时间比较紧张，还不能得出非常确切的结论。 关键词：水热法；石墨烯；复合光催化剂 Adsorption phase reaction technique for the preparation of graphene multi-component catalyst carrier Abstract: The purpose of our experiment is to prepare the GO and tetrabutyl titanate by using the hydrothermal method. Then they will get the composite photocatalyst of TiO2/GO. The creative point of our experiment is to do a research for whether it can degrading phenol in the sea water system. Before we do the research we use the TEM transmission electron microscope, Fourier transform infrared spectrum, and ultraviolet diffuse reflection spectra analysis to find the characterization. And to observe and study its properties. Before we do the experiment, we make the phenol standard curve in the different concentrations, and we find that seawater concentration has no effects on the experiment. With adding to water more and more, finally we find that, the influence of TiO2 particles in the attached on the surface of the number and particle size. After a lot of preliminary experiments and experiments, we find that the catalyst has certain effect, but the degradation rate falls in half an hour because of catalyst deactivation. Due to the amount of experimental data is not enough, the experiment time is so tight, we still not definite the conclusion. Keywords: Hydrothermal method； Graphene；Composite photocatalyst 1 引言 1.1 研究背景及意义 近年来，光催化已经在越来越多的领域里面得到非常广泛的应用。人们也在环境绿化领域里面提出了非常多的见解和措施。首先碳元素作为大自然最基础的元素，碳元素能否有效利用就有着非常大的意义了。作为单层原子层的石墨烯有着非常多优异的性能，并且价格非常便宜，获得的途径也非常简单，这就为石墨烯的普及奠定了基础。我们利用改变高锰酸钾的量来制备GO3和GO4。使用TEM，XRD等手段来做催化剂的表征。作为极高强度的石墨烯，附上载体，即合成TiO2-GO纳米复合光催化剂，从而研究在紫外条件下，TiO2