九江网状红土中粘土矿物过渡相的矿物学特征及成因.docVIP

  九江网状红土中粘土矿物过渡相的矿物学 特征及成因# 殷科1，洪汉烈1,3，李荣彪1,4，韩文1，吴钰2，高文鹏1** 5 10 15 20 25 30 35 40 （1. 中国地质大学地球科学学院，武汉 430074； 2. 中国地质大学珠宝学院，武汉 430074； 3. 中国地质大学生物地质与环境地质国家重点实验室，武汉 430074； 4. 凯里学院旅游学院，贵州 凯里 556000） 摘要：为研究长江中下游网纹红土中粘土矿物过渡相的矿物学特征及成因，采用 X 射线粉晶 衍射（XRD）、傅里叶红外吸收光谱（FTIR）、以及高分辨透射电子显微分析（HRTEM）等现 代测试技术方法，对江西九江红土剖面网纹红土中粘土矿物过渡相开展系统、深入的研究。 X 射线粉晶衍射及红外吸收光谱分析结果表明，九江剖面网纹红土中粘土矿物组成主要有伊 利石和高岭石，少量蒙脱石和伊利石/蒙脱石及微量高岭石/蒙脱石混层矿物过渡相。在高分 辨透射电子显微镜下，可观察到蒙脱石晶层向高岭石晶层转化的现象。伊利石/蒙脱石过渡 相是伊利石向蒙脱石转化的过渡产物，而高岭石/蒙脱石过渡相则为蒙脱石向高岭石转化的 过渡产物，网纹红土中这两种过渡相的出现说明了粘土矿物风化演化的过程，即：伊利石→ 伊利石/蒙脱石混层矿物→蒙脱石→高岭石/蒙脱石混层矿物→高岭石的演化，同时表明网纹 红土形成于风化作用增强的温暖潮湿气候环境。 关键词：网状红土；九江；早中更新世；粘土矿物过渡相；矿物学特征及成因 中图分类号：P571 Mineralogy and Genesis of Mixed-layer Clay Minerals in the Jiujiang Net-like laterite Yin ke1, Hong Hanlie1,3, Li Rongbiao1,4, Han Wen1, Wu Yu2, Gao Wenpeng1 (1. Faculty of Earth Sciences, China University of Geosciences, WuHan 430074; 2. Institute of Jewellery, China University of Geosciences, WuHan 430074; 3. State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, WuHan 430074; 4. Institute of Tourism,Kaili University, GuiZhou KaiLi 556000) Abstract: Mineralogy and genesis were investigated using X-Ray diffraction (XRD), Fourier infrared absorption spectroscopy (FTIR) and high resolution transmission electron microscopy (HRTEM) to understand the mineralogy and its genesis significance of mixed-layer clay minerals in Jiujiang laterite section. XRD and FTIR results show that the net-like laterite sediments are composed of illite, kaolinite, minor smectite and mixed-layer illite-smectite and minor mixed-layer kaolinite-smectite. HRTEM observation indicates that some smectite layers have transformed into kaolinite layers in net-like laterite. Mixed-layer illite-smectite is a transition phase of illite transforming into smectite, and mixed-layer kaolinite-smectite is a transitional product relative to kaolinite and smectite. The occurrence of two mixed-layer clay species suggests that the w