改性纳米黑碳对棕壤有效态Cu、酶活性和微生物呼吸的影响.docVIP

  改性纳米黑碳对棕壤有效态 Cu、酶活性和 微生物呼吸的影响# 刘玉真，成杰民** 5 10 15 20 25 30 35 （山东师范大学 人口·资源与环境学院，济南，250014） 摘要：(MBC)对棕壤中有效态Cu、呼吸强度和酶活 性影响。结果表明，施入MBC降低了棕壤pH 值和有效态Cu含量，且随着MBC施入量的增加， 土壤有效态Cu含量逐渐降低；MBC的施入，提高了土壤脲酶活性，对过氧化氢酶活性有较 弱的抑制作用，对土壤呼吸作用的影响是先增强后减弱，培养后期，呼吸强度与对照无显著 性差异。相关性分析表明，过氧化氢酶活性与有效态Cu含量之间有极显著正相关关系，与 黑碳施入量之间有极显著负相关关系，土壤有效态Cu含量与黑碳施入量之间有极显著负相 关关MBC 对棕壤中Cu有较好的钝化效果，增加了土壤尿酶活性和土壤呼吸作用， 在Cu 污染土壤修复中具有一定的应用前景。 关键词：自然地理学；改性纳米黑碳；棕壤；铜；酶活性 中图分类号：X53 Study on the effects of Modified Nano-Black Carbon on Content of Bioavailable Cu(II)，enzyme and Microbial Activity in Brown Soil LIU Yuzhen, CHENG Jiemin (School of Population Resources and Environment, Shandong Normal University，Jinan，250014) Abstract: A culture experiment were carried out to study the effects of Modified Nano-Black Carbon on Content of Bioavailable Cu(II), enzyme and microbial Activity in Brown Soil. The results showed that during the treatment of 60 days Modified Nano-Black resulted in a decrease in soil pH and Bioavailable Cu concentration and its content decreased with the added content of Modified Nano-Black. MBC had a remarkable activation effect on soil urease activity and a weak inhibition on soil catalase activity. Soil respiration increased and then decreased during the treatment, and respiration rate had no significant difference from the untreated soil. Catalase activity were negatively correlated with soil Bioavailable Cu concentration, but positively correlated with the amount of Modified Nano-Black. Soil Bioavailable Cu concentration were positively correlated with the amount of Modified Nano-Black. It indicated that MBC increased the activity of soil urease and respiration. It has a great value in remediating copper-contaminated soils. Key words: Physical Geography；MBC；Brown Soil；copper；enzyme activity 0 引言 黑碳（Black Carbon）是生物体或化石原料的挥发分在不完全燃烧或高温热解时转化成 的产物 [1-2] ，是具有羧基、酚羟基、羰基等含氧功能团[3-4] 的芳香族化合物。改性纳米黑碳 40 （MBC）是黑碳制备过程中采用一定的制备工艺制备的粒径达到纳米级的黑碳，由于其巨 大的比表面积、高的活性点位以及优良的吸附性能，在环境污染治理领域得到了广泛的应用。 Yang 和 Sheng[5]用小