酸碱除灰对煅烧无烟煤结构与灰分的影响.pdfVIP

29 8 第 卷第 期 煤 炭 技 术 Vol.29,No.08 2010 8 年 期 Coal Technology August,2010 !!!! 煤炭转化 ! ! !!!! 酸碱除灰对煅烧无烟煤结构和灰分的影响 1 2 2 2 魏 超 ，任耀剑，孙 智，田 杰 （1. 中国矿业大学徐海学院，江苏 徐州 221008 ；2. 中国矿业大学材料科学与工程学院，江苏徐州 221116） : 摘 要采用X 射线和X 射线荧光光谱仪对经过常规NaOH-HCl 脱灰处理的煅烧无烟煤及灰分进行晶体结构、灰 分物相及灰分成份分析。结果表明：脱灰处理能脱出碳微晶层片内的灰分，使层面间距由0.34466 nm 减小至 0.34386 nm ，但同时对微晶单元具有一定的解体作用，微晶高度由10.78782 降至8.95094 nm ，层片碳环数由153 降 至123 个。灰分中各种元素的含量都有较大程度的降低。 : 关键词煅烧无烟煤，脱灰处理，微晶碳结构，灰分成份 中图分类号:TD98 文献标识码:A 文章编号:1008-8725 （2010）08-0170-03 Effect of Acid-base Deliming on Microcrystalline Structure and Ash Component of Calcined Anthracite 1 2 2 2 WEI Chao , REN Yao-jian , SUN Zhi , TIAN Jie （1. Xuhai College, China University of Mining Technology, Xuzhou 221008, China; 2. College of Materials Science Engineering, China University of Mining Technology, Xuzhou 221116, China） Abstract:Microcrystalline structure, ash phase and component of calcined anthracite that deliminged by normal NaOH-HCl treatment are analysed with XRD and XRF respectively. The results show that ash inside carbon microcrystalline lamellasome could been removed by deliming and decrease interplanar distance from 0.34466nm to 0.34386nm, all elements content of ash are obviously decreased at the meantime. The disadvantage factor is that deliming could disintegrated carbon microcrystalline structure slightly, height of crystallite