《Highly sensitive and selective dopamine biosensor based on 3,4,9,10-perylene tetracarboxylic acid functionalized graphene sheetsmulti-wall carbon nanotubesionic liquid composite film modified electrode》.ppt

1 Ladies and gentleman, Good afternoon, my name is Dingmang, it is a great honor for me to be here to do my presentation, today I will share you a paper form I have read recently 3 My presentation will cover the following four aspects * Reporter:XieFang Date：2016.01.21 Email:2516023573@ Literature Reports 东华理工大学化学生物与材料科学学院 Faculty of Biology, Chemistry and Material Science, East China University of Technology Highly sensitive and selective dopamine biosensor based on 3,4,9,10-perylene tetracarboxylic acid functionalized graphene sheets/multi-wall carbon nanotubes/ionic liquid composite film modified electrode (Xiuli Niu.Biosensors and Bioelectronics,2013) Northwest Normal University IF 6.409 Content Background 1 Experimental 2 Results and Discussions 3 Conclusion 4 Background ◆CNTs can enhance the detection sensitivity and improve reversibility as it can promote electron transfer. ◆IL not only acted as a suitable charge-transfer bridge to facilitate the electrode transfer rate but also exhibited excellent electrocatalytic ability and good anti-fouling ability. ◆ it is of importance to develop a rapid, simple, sensitive sensor for the detection of DA without interference by AA. ◆The modification of PTCA onto graphene sheets can not only separate the graphene sheets and maintain inherent electronic structure of graphene sheets but also provide a negatively-charged-COOH. Experimental ◆Reagents ◆ Apparatus ◆Synthesis： 1.Synthesis of graphene 2.Synthesis of PTCA-GS ◆Fabrication of PTCA-GS/MCNT/IL, MCNT/IL and PTCA-GS/IL modified electrodes Results and discussion 3.1 Characterization of GS, PTCA-GS and PTCA-GS/MCNT/IL composite film Fig. 1. (A) SEM image of graphene sheets, (B) TEM image of graphene sheets, (C) SEM image of PTCA -functionalized graphene sheets, (D) TEM image of PTCA-functionalized graphene sheets, (E) SEM image of PTCA-GS/MCNT/IL composite film and (F) TEM image of PTCA-GS/MCNT/IL composite film. 3.2. Electrochemical characteristics of the modi