High Performance Liquid Chromatography inductively coupled plasma mass spectrometry determination of bromate and bromide in flour.docVIP

 PAGE \* MERGEFORMAT 11 High Performance Liquid Chromatography inductively coupled plasma mass spectrometry determination of bromate and bromide in flour Study: Liu Wei Li Bing Xia Yang Xu Siqi [Abstract] A high performance liquid chromatography inductively coupled plasma mass spectrometry (HPLC ICPMS) coupled with the flour samples was measured with the Br-BrO-3 method. ICS A23 column chromatography using bromine form to 30 mmol / L (NH4 ) 2CO3 as the mobile phase, pH 8, flow rate 0.8 mL / min, injection volume 1.0 mL. Under these conditions, BrO-3 and Br-the method detection limit (total Br) were 0.052 and 0.048 μg / L . to meet the form of flour, Trace Determination of bromine. on the 3 different sample preparation methods (ultrasonic, water bath and the oscillation of water extraction) were compared, and ultimately determine the oscillation of water extract of flour 1 h pretreatment method, the shape recovery rate was 93% ~ 111%, and the amount of various forms of bromine and consistent with the standard value, the standard values #8203;#8203;are within the scope of allowable error. use this method in commercial samples of 10 kinds of flour bromine forms were determined, the samples were not detected in the BrO-3. [Key Words] high performance liquid chromatography inductively coupled plasma mass spectrometry, bromine forms, flour 1 Introduction Mainly bromine bromide, bromate and organic bromine form. Bromide ion almost no toxicity to humans, and bromate were IARC as a 2B class of potential carcinogens released In 1992 the World Health Organization review of the use of safety KBrO3 identified in the report, BrO-3 is an oxidizing carcinogen, the main cause kidney and bladder tissue of animals to cancer; excessive consumption will damage a person’s blood, central nervous system and kidneys. Some studies have shown long-term consumption of drinking water with bromate, the cancer rate of parts per million [1]. KBrO3 bread flour in the flour as re