八组元高熵合金的组织及晶体结构的研究.doc

八组元高熵合金的组织及晶体结构的研究 摘 要：传统意义上的合金是为了满足某些主要性能来选择一种或两种元素为主体元素，添加其他辅助元素来提高其主要性能及某些次要性能以达到使用要求。如以铝元素为主的铝合金，以镁元素为主的镁合金，以及最常见的以铁为主的钢铁材料等。而高熵合金作为近年来兴起的新型合金材料，最大的特点就是不再局限于传统意义上合金的以一种或两种元素为主体元素的构成方式，从而发展成为一种新型的合金。 多组元高熵合金是以五种或五种以上金属元素以近摩尔比经熔炼、烧结等方法制造出来并具有金属性质的合金材料。没有某一种元素占主导地位，更多的是显示出了集体的特点。元素的增多使合金产生了高熵效应，使高熵合金具有十分广阔的应用前景。 本论文选取AI、Co、Cr、Fe、Ni、Mo、Si、Ti八种常用的金属元素，研究了不同成分高熵合金的制备、组织和结构，其中包括等摩尔比的八组元和改变Mo、Ti、Si摩尔比为原来的一半，利用真空熔炼方法制备合金样品。之后采用X射线衍射仪分析合金的相结构，合金的微观组织则采用光学显微镜和扫描电子显微镜，并利用维氏硬度机测定了合金的显微硬度HV。 关键词：高熵合金，晶体结构，组织 The Microstructure and Crystal Structure Studies on the Eight Elements of High-entropy Alloy Abstract：The conventional strategy for developing alloy is to select one or two elements as the principal, and then to add other minor elements for improving its main properties and other kinds of minor properties. such as Al-based aluminum alloy, Me-based magnesium alloy and the most common iron-based iron and steel materials. Multi-elemental high-entropy alloy has drawn extensive attentions in the past decades. As a new type of alloy , its biggest feature is the breakthrough of the traditional alloy that only one or two kinds of metal based design framework, developed a new alloy design concept. High-entropy alloys based on equal molar or nearly equal molar ratio five or more than five key elements, taking melting, sintering or other means to get a combination of the metallic material. No one element dominates, more is shown the characteristics of collective. The increase of the key elements lead to produce high-entropy effect, its makes high entropy alloys has very broad application prospects. This paper selected the AI, Co, Cr, Fe, Ni, Mo, Si, Ti eight kinds of commonly used metal elements, to study the composition of different preparation, organization and structure of high entropy alloys, including equal mole ratio of eight groups and change the Mo, Ti, Si mole ratio to half the original, using the method of vacuum smelting alloy samples preparation. then using X ray diffr