甲基丙烯酸锂及稀土化合物lacl3改性乙烯—醋酸乙烯酯橡胶的研究-study on modification of ethylene-vinyl acetate rubber by lithium methacrylate and rare earth compound lacl 3.docxVIP

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甲基丙烯酸锂及稀土化合物lacl3改性乙烯—醋酸乙烯酯橡胶的研究-study on modification of ethylene-vinyl acetate rubber by lithium methacrylate and rare earth compound lacl 3.docx

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甲基丙烯酸锂及稀土化合物lacl3改性乙烯—醋酸乙烯酯橡胶的研究-study on modification of ethylene-vinyl acetate rubber by lithium methacrylate and rare earth compound lacl 3

StudyonModificationofEthylene-VinylAcetateRubberbyLithiumMethacrylateandLaCl3ABSTRACTThesaltsofunsaturatedcarboxylicacidsareeffectivereinforcingagentsforrubbers.Inthisdissertation,thereinforcementofethylene-vinylacetaterubber(EVM)byasaltofunsaturatedcarboxylicacidLithiumMethacrylate(LiMAA)wasstudied.ThecuringpropertiesofEVMcompounds,themechanicalpropertiesandcrosslinkingstructureofEVMvulcanizateswerestudiedindetail.Then,effectsofrareearthcompoundLaCl3ontheEVM/LiMAAsystemwereinvestigated.EVM/LiMAA/LaCl3systemwascomparedwithEVM/LiMAAsystemoncuringproperties,mechanicalproperties,crosslinkingstructure,agingresistanceandelectricproperties.Themechanismoftheeffectswerealsoexplored.Firstly,throughtheneutralizationofmethacrylicacid(MAA)andLiOH,LiMAAwasinsitupreparedinEVMcompound.TheresultsshowedthatLiMAAhadgoodreinforcingeffectsonEVMvulcanizates.ThecuringratesofEVMcompoundsweregreatlyacceleratedwiththeincreaseofLiMAAcontent.TheioniccrosslinkdensityandgrossdensityofEVMvulcanizatesalsoobviouslyincreased,andcovalentcrosslinkdensityisthemainpartofthegrosscrosslinkdensity.TheeffectsofLiMAAcontentandLiOH/MAAmolratioonthemechanicalpropertiesofEVMvulcanizateswerestudied.Theformulationof3.0phrDCP,30phrLiMAAandLiOH/MAAmolratio1.0isrecommendedforEVMvulcanizatewithgoodmechanicalproperties.Thetensilestrength,tearstrengthandelongationatbreakare30.9MPa,93.4kN·m-1and383%,respectively.ScanningElectronicMicroscope(SEM)observationindicatedthatnanoscaleparticlesdisperseuniformlyinEVMvulcanizateswiththesizerangingfrom101nmto102nm.Secondly,LaCl3waschosenasamodifiertotheEVM/LiMAAsystem.WhentheLaCl3contentwasnotmorethan20phr,thecovalentcrosslinkdensityandgrossdensityofEVMvulcanizatesslightlydecreasedwiththeincreaseofLaCl3content,butioniccrosslinkdensityincreased.IoniccrosslinkdensitybecamemainpartofthegrosscrosslinkdensitywhentheLaCl3contentwas20phr.MechanicalpropertiesofEVMvulcanizatesdecreasedtosomeextentwiththeadditionofLaCl3.ButafteraginginairtheEVM/LiMAA/LaCl3vulcanizatehadmuchbettermaintenanc