二硫化钼(MoS2)基复合纳米材料的制备及其电化学储锂性能研究-材料学专业论文.docxVIP

摘要 保持在 592 mA h g-1。 关键词: 二硫化钼 导电材料 微米花 气凝胶 负极材料 锂离子电池 II Abstract Development and application of electric vehicles (EVs) can effectively relieve the worldwide pollution and energy crisis. Lithium-ions batteries (LIBs), with its advantages of high energy density, long cycle life and environmental friendliness, have been regarded as the most promising candidate for the next-generation energy storage device. However, the application of LIBs in the EVs/HEVs is hampered by the commercial graphite anode, whose theoretical capacity is limited to 372 mA h g-1. So, as a result, significant effort has been devoted to exploit alternative anode materials with higher capacities. Molybdenum disulfide (MoS2) is the focus of recent research interest owing to its high theoretical capacity (～670 mA h g-1). Molybdenum disulfide (MoS2) has a typical layered structure held together by weak van der Waals forces, which is similar to graphite. The adjacent layers spacing of MoS2 is 0.615 nm, significantly larger than that of graphite (0.335 nm). Due to these desirable properties, MoS2 can be easily intercalated by lithium ions. Therefore, it can be regarded as a superior electrode material for LIBs. However, the performance of bulk MoS2 is still unsatisfactory when used as anode materials in LIBs, suffering from rapid capacity fading because of its poor electrical/ionic conductivity and drastic volume change upon Li+ insertion/extraction. To solve the problems mentioned above, we have conducted work of the following aspects. In the first work, three-dimensional (3D) hierarchical MoS2/polyaniline (PANI) microflowers were successfully fabricated via a simple hydrothermal method. The crystal structure and morphology of the MoS2/PANI microflowers were characterized by SEM, TEM, XRD, XPS, and FT-IR spectra. The excellent electrochemical performance of the 3D hierarchical MoS2/PANI microflowers was demonstrated. Further 3D hierarchical MoS2/C microflowers can be prepared conveniently by anneali