碱性燃料电池用多氟聚噁二唑芳醚阴离子交换膜的制备与表征-高分子化学与物理专业论文.docxVIP

湘潭大学 湘潭大学 2009 级硕士学位论文 II II Abstract Fuel cells convert the chemical energy of a reaction directly into electrical energy, have attracted considerable attention due to their high efficiency, high power density and environment friendly, are considered to be one of the most promising power supply devices. Combined the advantages of PEMFCs with alkaline fuel cells, alkaline electrolyte membrane fuel cells (AEMFCs) have been attracting widely interest. When changing acidic medium into a basic one, AEMFCs have the potential to address many problems exist in PEMFCs while keeping higher power and energy density. The anion exchange membranes (AEMs) is the key component of fuel cells. It serves as the partition that separates the fuel from the oxidant and the support of catalyst. For AEMFCs applications, AEMs should possess necessary conductivity, dimension stability and excellent solubility for MEA preparation. However, most of commercial AEMs can not apply to AEMFCs for now. In order to obtain high performce AEMs for AEMFCs, we prepared two series of fluorinated poly(arylene ether-1, 3, 4-oxadiazole)s anion exchange membranes by copolymerization, functionalization by NBS and following amination with trimethylamine and N-methyl imidazole, respectively. The detail work present as follows: A novel high molecular weight linear polymer were synthesized via the copolymerization of tetramethyl bisphenol A(TM-BPA) and 2, 5-bis(2, 3, 4, 5, 6-penta?uorophenyl)-1, 3, 4-oxadiazole (FPOx) at mild condition such as room temperature, K2CO3 as catalyst. The molecular weight and distribution of the copolymers were studied at different reaction time. The brominated polymers were obtained by functionalization with NBS, the degree of functionality (DF) was investigated by the amout of NBS used. The chemical structures of the resulting polymers were confirmed by NMR, FT-IR and GPC. A series of fluorinated poly(aryl ether oxadiazole)s ionomer with pendant quaternary ammonium groups (QFPAEO-x)