NdLa002Lu098VO4晶体生长与性能研究.docxVIP

Nd:LaO. 02Lu0. 98V04晶体生长与性能研 究 王伟男李光伟赵斌 福州大学石油化工学院福州大学化学学院 摘要： 利用提拉法生长Nd:La0.02LU0.(jsVO,单晶。经测试，晶体的晶胞参数a=b=0. 7037 nm, c=0. 6242 nm;a向和c向的热膨胀系数分别为a =4. 32X10 V和a =11. 6X10 6 L。室温下测试偏振吸收和荧光光谱，结果显示：晶体在809 nm处有较大的吸收 线宽 5. 00 nm (。)和 6. 15 nm (n),较大的吸收截面 4. 70X 10 20 cm2 (0)和 10.47X10切cm2 (n) o在1065 nm处有强荧光发射峰,半峰宽分别为2. 27 nm (0)和1.82 nm (兀),受激发射截面。°分别为6.51X10^19 ) cm2(0 )和 13.8X10^19 ) cm2 ( n ),荧光寿命为102. 5 us。利用未镀膜的晶片进行初步 激光实验，获得1065 nm连续和调Q激光输出。在最高泵浦功率20 W时，获得 最高4. 95 W的连续输出，光-光转换效率为24. 75%,斜效率27. 9%;在脉冲重复 频率为5 kHz时,得到最高的峰值功率为61.99 kWo结果表明,Nd:Lao.o2Luo.98VO4 晶体可能成为新的脉冲激光晶体。 关键词： Nd:LaO. 02Lu0. 98V04晶体;光谱;脉冲激光; 作者简介：赵斌(1974-)，副教授，主要从事激光和拉曼晶体材料方面研究， HYPERLINK mailto:tigerzhao@fzu.edu.cn tigerzhao@fzu.edu.cn 收稿日期：2017-09-14 基金：福州大学人才基金(XRC-1304);福州大学科技发展基金(2013-XQ-6) Growth and properties of Nd:La0. 02Lu0. 98V04 crystal WANG Weinan LI Guangwei ZHAO Bin College of Chemical Engineering, Fuzhou University; College of Chemistry, Fuzhou University; Abstract： The Nd:La0.02Lu0.9sVO.i single crystal was grown by the Czochralski method. The cel 1 parameters of the crystal are a=b=0. 7037nm, c=0. 6242nm, and thermal expansi on cocff ici cnts along a and c ax i sar e a a-4. 32X10 ^K1 and a c=ll. 6X 10 K. Polarization absorption spectra and fluorescence spectra were measured at room temperature, which indicates that a large absorption line width at 809nm is 5. 00 nm ( o ) and 6. 15 nm (n) , with a large absorption cross section of 4. 70X 10 20 cm2 ( o ) and 10.47X10 cm (n) 、 rcspec tivc ly. The FW11M of strong fluorescence emission peaks at 1065 nm is 2. 27 nm (o ) and 1. 82 nm (开)? In correspondly, the stimulated emission cross section o e is 6. 51 X 10 -19 ) cm2 ( o ) and 13. 8X 10 -19 ) cm2 (n) , as the fluorescence life time is 102. 5 □ s. A CW and Q-Switched laser output has been obteiined at 1065 nm by uncoated crystai si ices in prelim in ary laser experime nt s. The highes t CW output power attained to be 4. 95 W with the optical-optical conversion efficiency of 24.75% an