甲醇在PtZSM-5上催化氧化动力学.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184298 甲醇在Pt/ZSM-5上催化氧化动力学 张兴1，杨卫娟1，苏佳乐1，王业峰1，赵庆辰1，周俊虎1 （1浙江大学能源清洁利用国家重点实验室，浙江 杭州310027 ） 摘 要：在内径为4mm的石英管燃烧器中进行了富氧条件下甲醇在Pt/ZSM-5上的深度氧化动力学实验，反应温度控制在388K以下，构建了Power law模型和Langmuir-Hinshelwood模型来表征甲醇的低温深度氧化反应，Power law模型和Langmuir-Hinshelwood模型的活化能分别为66.09 kJ·mol-1和65.55 kJ·mol-1，甲醇和氧气的反应级数分别为-0.14和1.23，Langmuir-Hinshelwood模型中，甲醇的吸附常数比氧气的吸附常数大，说明甲醇在催化剂表面的吸附能力比氧气强，提高氧气的浓度比提高甲醇的浓度更有利于促进反应速率，这一点同样反映在氧气的反应级数比甲醇的反应级数大。 关键词：甲醇；催化；转化率；动力学；活化能； 中图分类号：TK16 文献标志码：A 文章编号： Kinetics of methanol oxidation over Pt / ZSM-5 Catalyst ZHANG Xing1, YANG Weijuan1 , SU Jiale1, WANG Yefeng1, ZHAO Qingchen1, ZHOU Junhu1 (1State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, Zhejiang Province, China) Abstract: The kinetics of methanol deep oxidation over Pt / ZSM-5 catalyst was carried out under oxygen-rich conditions in a quartz tube burner with an inner diameter of 4 mm. The reaction temperature was controlled below 388K. The Power-rate law model and the Langmuir-Hinshelwood model are established to characterize the methanol deep oxidation for the low-temperature. The activation energy catalytic oxidation is 66.09 kJ·mol-1 and 65.55 kJ·mol-1 for the Power law model and the Langmuir-Hinshelwood model respectively. The order of reaction for methanol and oxygen is -0.14 and 1.23 respectively. In the Langmuir-Hinshelwood model, the adsorption constant of methanol is larger than oxygen, indicating that the methanol adsorption capacity of the catalyst surface is stronger than oxygen. Raising the concentration of oxygen concentration is more conducive to promoting the reaction rate than methanol, which is also reflected in the reaction order of oxygen is larger than methanol. Key words: methanol; catalytic; conversation; kinetics; activation energy; 0 前言 甲醇是一种优质的可再生燃料，可以实现内燃机的经济、高效、清洁燃烧，