钴系复合氧化物及脉冲电弧放电分解n2o的实验分析-experimental analysis of n2o decomposition by cobalt-based composite oxides and pulsed arc discharge.docxVIP

华中科技大学硕士学位论文华中科技大学硕士学位论文IIII对该催化剂的催化活性影响不大。（5）脉冲电弧放电 PAC 对 N2O 有一定的处理效果，但 PAC 对放电生成物的选 择性较差。Ce1-xZrxO2 复合氧化物的加入可以提高 N2O 的处理效果及生成物的选择 性，减少 NOx 的产生。脉冲电弧放电 PAC 联合钴系复合氧化物催化分解 N2O 时， 由于 NOx 的产生，催化剂的催化活性均有明显不同程度的降低。关键词：催化分解；复合氧化物；Ce；碱金属；脉冲电弧放电IIIIIIAbstractUnder the circumstance of nitrogen oxide emission and carbon emissions abatement, the study of nitrous oxide (N2O) abatement technology become a significant subject, which nitrous oxide is not only a kind of greenhouse gas to impact climate, but also contributes to the destruction of the ozone layer in the stratosphere. Direct catalytic decomposition of N2O is considered as a perfect method to decompose N2O to N2 and O2 without accretion that has received much attention.In this work, a series of catalysts were prepared by sol-gel method to replace Co2+ byZn2+, dropping Ce into cobalt–zinc mixed oxide catalysts and used cobalt–zinc-cerium mixed oxide catalysts as the carriers of the catalysts to load potassium oxide by impregnation method, tested for the catalytic decomposition of N2O in the N2O+N2 system. In addition, a series of CexZr1-xO2 were prepared by sol-gel method for the synergistic system of catalyst and discharge plasma to reduce N2O. X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) and Infrared and Raman spectroscopy (Raman) were used to characterize the catalysts. The results as followed:Mg2+ and Zn2+ could replace partially the Co2+ into the spinel structuresuccessfully, but only a part of Ni2+ and Cu2+ could introduce into spinel structure promote the formation of spinel phase. In our studies, the Zn0.5-Co presented the best behavior in the decomposition of N2O.The catalytic activity of cobalt mixed oxide depended on the degree of Co2+substituted by metal cation which could affecte the formation of crystal and degree of crystallinity and dimension and change the chemical state of cobalt element and weaken the Co-O bond and facilitate the desorption of ad